Scotland (my home turf) is full of routes. For starters there's the West Highland Way (and the still to be claimed double) and this can be linked to the Great Glen Way to give approx 170 miles of pretty stunning riding. Also it's possible to ride across to Dalwhinnie from either Fort William or via the Corriearick Pass and then into the Cairngorms and East Coast or out to the Moray Firth via the Speyside Way. There's also the Kintyre Way - if you google bikepacking the Kintyre way there's a good post out there. In the South you could do the Southern Upland Way, rode some of this on Trans-Scotland a few years back and it's more remote and better than you would think.
Just a few suggestions.....